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Melting plastic into gasoline at oven temperature

Plastic bags to gasoline — at kitchen oven temperature, utilizing inexpensive aluminum salt. Oak Ridge produced 60% gasoline. The last hitch is just water.

Melting plastic into gasoline at oven temperature

The old ways were expensive on purpose.

Polyethylene—the plastic that we use in shopping bags and white cutting boards—is one of the most common materials on Earth and one of the hardest materials to recycle. The standard route to convert it into fuel is pyrolysis: heating the plastic to roughly 450-500 degrees Celsius to shatter its long molecular chains into smaller hydrocarbons. The heat, plus the noble-metal catalysts and solvents most methods lean on, is exactly what makes plastic fuel hard to justify at scale.

What Oak Ridge did differently

The ORNL team skipped almost all of it. They mixed the plastic into molten salts containing aluminum chloride, and then those salts do two jobs at once, serving as both the liquid in which the reaction happens and the catalyst that drives it. Charged aluminum atoms form highly acidic sites that attack polyethlene's chains and snap them into fuel-sized pieces. Simpler chains yield gasoline-like compounds, and the more complex ones produce diesel.

The headline numbers are about 60% gasoline yield, a reaction temperature below 200 degrees, comparable to a conventional kitchen oven, and less than half the head pyrolysis demands. No noble metals, no external hydrogen, no organic solvent, and no chemical initiator to kick things off. Cheap, commercially available salt doing the work of a much more expensive setup.

So, what's the catch?

The aluminum salt system is inexpensive and chemically active, but it's hygroscopic, meaning it soaks up water from the air, and that moisture degrades its stability. Solving that is the next big problem. The researchers want to confine the salts, possibly with halogens or carbon-based materials, to make them steadier and easier to separate out. Until that's cracked, this stays a lab result, not a fully functioning refinery.

Why the number still matters

Waste plastic is one input the world will just never run short of, and the catalyst here is dirt cheap; that combination—abundant feedstock, low-cost catalyst, and oven-level heat—is the reason a lab-scale yield is worth paying attention to. Whether it scales depends entirely on the water problem. But the economics of turning trash into transportation fuel just got a lot less lopsided, well, at least on paper.

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